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Arbeitskreis van Eldik

1995-1999

 

1995

361. Transition metal catalyzed oxidation of sulfur(IV)-oxides. Atmospheric-relevant processes and mechanisms
C. Brandt and R. van Eldik
Chem. Rev., 95, 119-190 (1995)

362. Mechanistic study of the coordination of hydrogen peroxide to me­thylrhenium trioxide
O. Pestovsky, R. van Eldik, P. Huston and J.H. Espenson
J. Chem. Soc. Dalton Trans., 133 (1995)

363. Pressure effects on the rates of Hg2+-assisted chloride release from some [CrCl(di­amine)(triamine)]2+ complexes
D.A. House and R. van Eldik
Inorg. Chim. Acta, 230, 29 (1995)

364. Temperature and pressure effects on the kinetics of the bromate ion – iodide ion – L ascorbic acid clock reaction
I. Fabian and R. van Eldik
Int. J. Chem. Kinet., 27, 491 (1995)

365. Substitution reactions of trans-[Ru(NH3)4(P(OEt)3)(H2O)]2+ revisited. Mechanistic elucidation from a volume profile analysis
B.S. Lima Neto, D.W. Franco and R. van Eldik
J. Chem. Soc., Dalton Trans. 463, (1995)

366. Kinetics and mechanism of halogen-bridge cleavage in dimethylamino­methyl-phenyl-C,N pallada- and platinacycles by pyridines. Pressure effects and X-Ray structural characterization of the N,N-cis-[Pt(o-C6H3(4-MeO)CH2NMe2)-Cl(py)] reaction product, its N,N-trans-[Pt(o-C6H4C(Me)=NOH)Cl(py)]orthome-tallated analog and trans-[(Bun3P)IPd(μ-I)2Pd(PBun3)I], the dimer of similar reactivity
A.D. Ryabov, L.G. Kuz’mina, V.A. Polyakov, G.M. Kazankov, E.S. Ryabova, M. Pfeffer and  R. van Eldik
J. Chem. Soc., Dalton Trans., 999 (1995)

367. Kinetic evidence for the redox cycling of Mn(II/III) in the presence of N-nitroso­ hy­droxyl-amine-N-sulfonate in aqueous medium
F.F. Prinsloo, J.J. Pienaar and R. van Eldik
J. Chem. Soc., Dalton Trans., 293 (1995)

368. Steric control over the complex-formation and chelation kinetics of cis-bis(amine)-palladium(II) complexes with methionine and S-methyl-cysteine in weakly acidic aqueous solution
S. Suvachittanont and R. van Eldik
J. Chem. Soc., Dalton Trans., 2027 (1995)

369. New optical cell design for laser flash photolysis studies in supercritical fluids
Q. Ji, E.M. Eyring, R. van Eldik, K. Bal Reddy, S.R. Goates and M.L. Lee
Rev. Sci. Instrum., 66, 222 (1995)

370. Complex-formation reactions of aquacobalamin revisited: effect of chloride on the observed rate and activation parameters
F.F. Prinsloo, E.L.J. Breet and R. van Eldik
J. Chem. Soc., Dalton Trans., 685 (1995)

371. Spontaneous aquation reactions of a promising tumor inhibitor trans-imidazolium-tetrachlorobis(imidazole)ruthenium(III), trans-HIm[RuCl4(Im)2]
J. Chatlas, R. van Eldik and B.K. Keppler
Inorg. Chim. Acta, 233, 59 (1995)

372. Pressure tuning voltammetry. Reaction volumes for electron transfer in cyto­chro­me c and ruthenium-modified cytochrome c
J. Sun, J.F. Wishart, R. van Eldik, R.D. Shalders and T.W. Swaddle
J. Am. Chem. Soc., 117, 2600 (1995)

373. Use of high pressure techniques for measuring reaction rates in liquid solutions
C.D. Hubbard and R. van Eldik
Instrum. Sci. Techn., 23, 1 (1995)

374. Influence of  α-subunits on the high-pressu­re stabi­lity of apo and holo β2-subunits in the bienzyme complex tryptophan synthase from Escherichia coli
S. Sindern, R. van Eldik and P. Bartholmes
Biochemistry, 34, 1959 (1995)

375. Equilibria in Chemistry
R. van Eldik
Editorial in GIT Fachz. Lab. 39, 83 (1995)

376. Activation parameter correlations for nucleophilic additon to (μ2-H)2Os3(CO)10
A. Neubrand, A.J. Poe and R. van Eldik
Organometallics, 14, 3249 (1995)

377. Temperature, pressure and solvent isotope effects on the precursor formation constant and reorganization dynamics in outer-sphere charge transfer between free mobile [Fe(CN)6]3- and [Fe(CN)6]4- ions
D.E. Khoshtariya, R. Billing, M. Ackermann and R. van Eldik
J. Chem. Soc., Faraday Trans., 91, 1625 (1995)

378. A functional model for carbonic anhydrase. Thermodynamic and kinetic study of a tetraazacyclododecane complex of zinc(II)
X. Zhang and R. van Eldik
Inorg. Chem., 34, 5606 (1995)

379. Formation and deoxygenation kinetics of oxyhemerythrin and oxyhemocyanin. A pressure dependence study
H.-D. Projahn, S. Schindler, R. van Eldik, D.G. Fortier, C.R. Andrew and A.G. Sykes
Inorg. Chem., 34, 5935 (1995)

380. Complex-formation reactions of dichloro(L-methionine)palladium(II) with inosine and inosine 5′-monophosphate. Labilization induced by S-donor chelate
F.F. Prinsloo, J.J. Pienaar and R. van Eldik
J. Chem. Soc., Dalton Trans., 3581 (1995)

381. Electronically tuned trans-labilization controls the substitution behaviour of rhodo-ximes
C. Dücker-Benfer, R. Dreos and R. van Eldik
Angew. Chem., 107, 2414 (1995)
Angew. Chem. Int. Ed. Engl., 34, 2245 (1995)

382. Laser flash photolysis studies of metal carbonyls in supercritical CO2 and ethane
Q. Ji, E.M. Eyring, R. van Eldik, K.P. Johnston, S.R. Goates and M.L. Lee
J. Phys. Chem., 99, 13461 (1995)

383. The reaction of aquapentaamminerhodium(III) with carbonate in strongly basic solution – A multiple choice of potential interactions resolved
E. Cloete, E. Breet and R. van Eldik
J. Chem. Soc., Dalton Trans., 3591 (1995)

384. Leaving group effects on ligand substitution reactions of pentacyanoferrate(II) complexes: rate constant and activation volume correlation
S. Alsheri, J. Burgess, R. van Eldik and C.D. Hubbard
Inorg. Chim. Acta, 240, 305 (1995)

1996

385. Correlation between kinetic and thermodynamic complex-formation constants for the interaction of bis(amine)palladium(II) with inosine, inosine 5′-monophosphate and guanosi­ne 5′-monophosphate
M. Shoukry and R. van Eldik
J. Chem. Soc., Dalton Trans., 2673 (1996)

386. Mechanistic insight from kinetic studies on the interaction of model palladium(II) complexes with nucleic acid components
T. Rau and R. van Eldik
in „Metal Ions in Biological Systems, Vol. 32, Interactions of Metal Ions with
Nucleotides, Nucleic Acids, and their Constituents“, H. Sigel and A. Sigel (Eds.),
Marcel Dekker, New York, 339 (1996).

387. Correlation between kinetic and thermodynamic complex-formation constants for the interaction of bis(amine)palladium(II) with inosine, inosine 5′-monophosphate and guanosi­ne 5′-monophosphate
M. Shoukry and R. van Eldik
J. Chem. Soc., Dalton Trans., 2673 (1996)

386. Mechanistic insight from kinetic studies on the interaction of model palladium(II) complexes with nucleic acid components
T. Rau and R. van Eldik
in „Metal Ions in Biological Systems, Vol. 32, Interactions of Metal Ions with
Nucleotides, Nucleic Acids, and their Constituents“, H. Sigel and A. Sigel (Eds.),
Marcel Dekker, New York, 339 (1996).

387. Comparative rates of ligand substitution reactions of Pt-C bonded complexes in aqueous solution and the x-ray structure of [Pt{C6H3(CH2NMe2)2-2,6}(OH2)]-[O­SO2CF3]
M. Schmülling, D.M. Grove, G. van Koten, R. van Eldik, N. Veldman and A.L. Spek
Organometallics, 15, 1384 (1996)

388. Volume of activation for the self-exchange reaction of cytochrome c
M. Meier and R. van Eldik
Inorg. Chim. Acta, 242, 185 (1996)

389. Mechanistic information on ligand substitution reactions of europium(III) in aqueous solution from high pressure stopped-flow experiments
Y. Shi, Q. Ji, E.M. Eyring and R. van Eldik
J. Chem. Soc., Dalton Trans., 2127 (1996)

390. Novel building blocks for biomimetic assemblies. Synthesis, characterization, spectroscopic and electrochemical properties of new bidentate ligands derived from   lysine and cysteine and their complexes with bis(2,2′-bipyridine)ruthenium(II)
R. Alsfasser and R. van Eldik
Inorg. Chem., 35, 628 (1996)

391. An unified mechanistic view obtained from the temperature and pressure depen­dence of the spontaneous, acid-, and base-assisted cyclometallation reactions of dirhodium(II) complexes
F. Estevan, G. Conzales, P. Lahuerta, M. Martinez, E. Peris and R. van Eldik
J. Chem. Soc., Dalton Trans., 1045 (1996)

392. Influence of mixed sulfur-nitrogen-oxides on the redox kinetics of iron ions in aqueous solution
V. Lepentsiotis, F.F. Prinsloo, R. van Eldik and H. Gutberlet
J. Chem. Soc., Dalton Trans., 2135 (1996)

393. Comparative kinetic analysis of reversible intermolecular electron-transfer reactions between a series of pentaammineruthenium complexes and cytochrome c
M. Meier, J. Sun, J.F. Wishart and R. van Eldik
Inorg. Chem., 35, 1564 (1996)

394. Reaction mechanism of phenanthroline derivatives chelating Mo(CO)5 deduced from pulsed photolysis in several solvents at high pressure
S. Cao, Y. Shi, J. Hollmann, R. van Eldik and E.M. Eyring
J. Chem. Soc., Dalton Trans., 1629 (1996)

395. Synthesis and characterization of highly fluorinated tungsten(II) metallocyclopropane complexes. Kinetics and mechanism of an unprecedented η2-vinyl isomeriza­tion
J.L. Kiplinger, T.G. Richmond, A.M. Arif, C. Dücker-Benfer and R. van Eldik
Organometallics, 15, 1545 (1996)

396. Mechanistic studies on the formation and decay of diiron(III) peroxo complexes in the reaction of diiron(II) precursors with dioxygen
A.L. Feig, M. Becker, S. Schindler, R. van Eldik and S.J. Lippard
Inorg. Chem., 35, 2590 (1996)

397. Tuning the reactivity of platinum(II) complexes through cyclometallation. A reply
M. Schmülling, A.D. Ryabov and R. van Eldik
J. Chem. Soc., Dalton Trans., 1471 (1996)

398. Formation of sulfur and sulfur-nitrogen compounds in the flue gas desulfurization plants and their influence on the oxidation kinetics of sulfite
H. Gutberlet, S. Finkler, B. Pätsch, R. van Eldik and F.F. Prinsloo
VGB Kraftwerktechnik, 76, 139 (1996)

399. Carbonic anhydrase catalysis. A volume profile analysis
X. Zhang, C.D. Hubbard and R. van Eldik
J. Phys. Chem., 100, 9161 (1996)

400. Outer-sphere redox reactions of [CoIII(NH3)5(HXPYOZ)](n-3)- complexes. A tempera­tu­re- and pressure-dependence kinetic study on the influence of the phosphorous oxoanions
M. Martinez, M.-A. Pitarque and R. van Eldik
J. Chem. Soc., Dalton Trans., 2665 (1996)

401. Theoretical study of the water exchange reaction on divalent zinc ion using densi­ty functional theory
M. Hartmann, T. Clark and R. van Eldik
J. Mol. Model., 2, 354 (1996)

402. Investigation of the uncatalyzed hydration of CO2 and the first approximations to the active site of carbonic anhydrase – A combined ab-initio and DFT study
M. Hartmann, T. Clark and R. van Eldik
J. Mol. Model., 2, 358 (1996)

403. Chemistry goes supercritical – A host of environmental friendly new possibilities for the chemical process industry
E. Breet, R. van Eldik and R. Steiner
Chemical Processing SA, August, 6 (1996)

404. Photo-substitution reactions of Cr(CO)4(1,10-phenanthroline). Mechanistic informa­tion from entering nucleophile, irradiation wavelength and pressure dependences
W.-F. Fu and R. van Eldik
Inorg. Chim. Acta, 251, 341 (1996)

405. Kinetics and mechanism of the reduction of 1,2-diaminocyclohexanetetraacetato-m­anganese(III) by hydroxylaminemonosulfonate and hydroxylaminedisulfonate
F.F. Prinsloo, J.J. Pienaar and R. van Eldik
J. Chem. Soc., Dalton Trans., 4393 (1996)

406. Review of the activities and achievements of the EUROTRAC subproject HALIPP
P. Warneck, P. Mirabel, G.A. Salmon, R. van Eldik, C. Vinckier, K.J. Wannowius       and C. Zetzsch
„Heterogeneous and Liquid-Phase Processes“, P. Warneck (Ed.), Springer, Chapter 2, 1996.

407. The interaction of SOX and NOY species in aqueous solution. Photo and metal ion catalysis
R. van Eldik, M. Geißler, C. Brandt and V. Lepentsiotis
„Heterogeneous and Liquid.Phase Processes“, P. Warneck (Ed.), Springer, 126 (1996)

408. Geometric factors in the structural and thermodynamic properties of copper(II) complexes with tripodal tetraamines
A.M. Dittler-Klingemann, C. Orvig, F.E. Hahn, F. Thaler, C.D. Hubbard, R. van Eldik, S. Schindler and I. Fabian
Inorg. Chem., 35, 7798 (1996)

1997

409. Formation of transient iron(III)-sulfur(IV) complexes revisited. Application of rapid-scan techniques
F.F. Prinsloo, C. Brandt, V. Lepentsiotis, J.J. Pienaar and R. van Eldik
Inorg. Chem., 36, 119 (1997)

410. Kinetic and thermodynamic study of the mechanism of reversible intermolecular electron-transfer reactions between horse heart cytochrome c and a series of co­balt imine complexes
M. Meier and R. van Eldik
Chemistry Eur. J., 3, 33 (1997)

411. Photo-substitution reactions of M(CO)4(1,10-phenanthroline) (M = Mo, W). In­fluence of entering ligand, irradiation wavelength and pressure
W.-F. Fu and R. van Eldik
Organometallics, 16, 572 (1997)

412. Probing the solvation properties of liquid versus supercritical fluids with laser flash photolysis of W(CO)6 in the presence of 2,2′-bipyridine
Q. Ji, C.R. Lloyd, E.M. Eyring and R. van Eldik
J. Phys. Chem., A, 101, 243 (1997)

413. Effect of pressure on inorganic reactions
C.D. Hubbard and R. van Eldik
in „Chemistry under Extreme or Non-Classical Conditions“, R. van Eldik and C.D. Hubbard (Eds.), Wiley/Spektrum, New York/Heidelberg, Chapter 2, 1997

414. Kinetic and thermodynamic measurements under pressure
D. Magde and R. van Eldik
in „High Pressure Techniques in Chemistry and Physics: a practical approach“,
N. Isaacs and W. Holzapfel (Eds.), Oxford University Press, Oxford, Chapter 6, 1997

415. Photochemical behaviour of metal complexes. Pressure effects versus mechanism
G. Stochel and R. van Eldik
Coord. Chem. Rev., 159, 153 (1997)

416. Outer-sphere redox reactions of (N)5-macrocyclic cobalt(III) complexes. A tempe­rature and pressure dependence kinetic study on the influence of size and geome­try of different macrocycles
M. Martinez, M.-A. Pitarque and R. van Eldik
Inorg. Chim. Acta, 256, 51 (1997)

417. Anionopetaaminecobalt(III) complexes. 27. Activation volumes for spontaneous and Hg2+-assisted chloride release reactions
J. Chatlas, D.A. House, A. Neubrand and R. van Eldik
Inorg. Chim. Acta, 257, 173 (1997)

418. Coordination and organometallic chemistry under extreme or non-classical condi­tions
R. van Eldik and C.D. Hubbard
New J. Chem., 21, 825 (1997)

419. Complex-formation and ligand substitution reactions of 2-picolylamine palladi­um(II) with various biologically relevant ligands. Characterization of 2-picolyla­mi­ne-(1,1-cyclobutanedicarboxylate)palladium(II)
T. Rau, M. Shoukry and R. van Eldik
Inorg. Chem., 36, 1454 (1997)

420. Reactivity of nucleophiles toward x-3-(p-tolylsulfonyl)-1,2,3-benzoxathiaole-2,2-dioxides: Kinetics, activation volumes, and mechanism
K.K. Andersen, C.D. Hubbard, A. Gerhard, R. van Eldik and M.G. Kociolek
J. Phys. Org. Chem., 10, 175 (1997)

421. Kinetics and mechanism of the reduction of hexacyanoferrate(III) by myoglobin in aqueous solution
E. Ilkowska, R. van Eldik and G. Stochel
J. Biol. Inorg. Chem., 2, 603 (1997)

422. Copper(III) pyrophosphate complexes in aqueous solution. A pulse radiolysis study at ambient and high pressure
D.E. Cabelli, J.F. Wishart, J. Holcman, M. Meier and R. van Eldik
J. Phys. Chem. A, 101, 5131 (1997)

423. Evidence for the unexpected associative displacement of adenosyl by cyanide in coenzyme B12
N.E. Brasch, M.S.A. Hamza and R. van Eldik
Inorg. Chem., 36, 3216 (1997)

424. Competing thermal and photochemical ligand substitution of the dimetallacycle (CO)4Mo(μ-PMD)2Mo(CO)4, PMD = pentamethylenediazirine. Mechanistic infor­mation from nucleophile and pressure dependences
W.-F. Fu, H. Kisch and R. van Eldik
Organometallics, 16, 3439 (1997)

425. Preferred coordination sites for metal fragments in σ,π-bimetallic complexes. Detailed mechanistic insights from heteroatom, bridging ligand, solvent, tempera­ture and pressure effects on the irreversible exchange of coordination sites
T.A. Waldbach, R. van Eldik, P.H. van Rooyen and S. Lotz
Organometallics, 16, 4056 (1997)

426. Kinetics and thermodynamics of the aquation of amminepentacyanoferrate(II). A volume profile analysis
I. Maciejowska, R. van Eldik, G. Stochel and Z. Stasicka
Inorg. Chem., 36, 5409 (1997)

427. Activation parameters for the decomposition of peroxynitrite and peroxynitrate, and their reduction by iodide. An insight into the detailed mechanism
S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski
J. Phys. Chem. A, 101, 7114 (1997)

428. Kinetics and mechanism of reduction of tris(acetylacetonato)manganese(III) by HONH(SO3) and HON(SO3)22- in aqueous solution
F.F. Prinsloo, J.J. Pienaar and R. van Eldik
J. Chem. Soc., Dalton Trans., 1871 (1997)

429. Application of extreme or non-classical conditions in chemistry
R. van Eldik and C.D. Hubbard
GIT Laboratory Journal, 1, 9 (1997)

430. Dynamics of CO binding to lacunar iron(II) cyclidene complexes
M. Buchalova, P.R. Warburton, R. van Eldik and D.H. Busch
J. Am. Chem. Soc., 119, 5867 (1997)

431. A mechanistic study of the reduction of quinones by ascorbic acid
N.S. Isaacs and R. van Eldik
J. Chem. Soc., Perkin Trans. 2, 1465 (1997)

432. Hydration and water exchange of zinc(II) ions. Application of density functional theory
M. Hartmann, T. Clark and R. van Eldik
J. Am. Chem. Soc., 119, 7843 (1997)

433. The formation of dithionate during the iron(III)-catalyzed autoxidation of sul­fur(IV)-oxides
C. Brandt and R. van Eldik
Atmos. Environm., 31, 4247 (1997)

434. Kinetics of FeII(edta) oxidation by molecular oxygen revisited. New evidence for a multistep mechanism
S. Seibig and R. van Eldik
Inorg. Chem., 36, 4115 (1997)

435. Fixation of CO2 by zinc(II) chelates in alcoholic medium. X-ray structure of {[Zn(cyclen)]33-CO3)}(ClO4)4 and [Zn(cyclen)EtOH](ClO4)2
A. Schrodt, A. Neubrand and R. van Eldik
Inorg. Chem., 36, 4579 (1997)

436. Formation of an association complex without a substitution reaction occurring between methylcobalamin and cyanide
N.E. Brasch, F. Müller, A. Zahl and R. van Eldik
Inorg. Chem., 36, 4891 (1997)

437. X-ray and solution structure of inosine 5′-monophosphate coordinated to (ethylene­diamine)palladium(II). The importance of intramolecular hydrogen bonding
T. Rau and R. van Eldik
Chem. Ber./Recueil, 130, 1551 (1997)

438. Kinetics and mechanism of substitution reactions of cis-[PtMe2(dmso)2] with pyridine
M. Schmülling and R. van Eldik
Chem. Ber./Recueil, 130, 1791 (1997)

439. Kinetics and mechanism of the Fe(III) complexation by lipophilic 3-hydroxy-2-methyl-1(γ-stearoamidopropyl)-4-pyridinone (HMSP)
Y. Shi, E.M. Eyring, R. van Eldik, G. Liu, F.W. Bruenger and S.C. Miller
J. Biol. Inorg. Chem., 2, 728 (1997)

440. Pyrolysis of plastics containing brominated flame retardants
B. Danzer, M. Riess, H. Thoma, O. Vierle and R. van Eldik
Organohalogen Compounds, 31, 108 (1997)

1998

441. Electron-transfer reactions under high pressure. Application of spectroscopic and electrochemical techniques
R. van Eldik
in „Photochemistry and Radiation Chemistry: Complementary Methods in the Study of Electron Transfer“, D. No­ce­ra and J.F. Wis­hart (Eds.), Advances in Chemistry Series Vol. 254, Chapter 19, Ame­ri­can Che­mi­cal Socie­ty, Wa­shing­ton, 1998

442. Pressure tuning photochemistry of metal complexes in solution
R. van Eldik and P.C. Ford
Advances in Photochemistry, Vol. 24, D.C. Neckers, D.H. Volman and G. von Bünau (Eds.), Wiley, New York, 61 (1998)

443. Kinetic analysis of the complexation of aqueous lanthanide(III) ions by arsenazo III
Y. Shi, E.M. Eyring and R. van Eldik
J. Chem. Soc., Dalton Trans., 967 (1998)

444. Systematic tuning of the photo-substitution mechanism of M(CO)4(1,10-phenan­throline) by variation of the metal, entering nucleophile, excitation wavelength and pressure
W.-F. Fu and R. van Eldik
Inorg. Chem., 37, 1044 (1998)

445. Thermal ring-closure reactions of pentacarbonylchromium complexes wirth biden­tate N-N ligands revisited. Elimination of side reactions and the elucidation of the intimate mechanism
C. Dücker-Benfer, F.-W. Grevels and R. van Eldik
Organometallics, 17, 1669 (1998)

446. Effect of pressure on the reversible binding of acetonitrile to the „Co(I)-CO2“ adduct to form Co(III) carboxylate
E. Fujita and R. van Eldik
Inorg. Chem., 37, 360 (1998)

447. Photochemistry of the triangular clusters Os3(CO)10(α-diimine). Homolysis of an Os-Os bond and solvent-dependent formation of biradicals and zwitterions
J. Nijhoff, M.J. Bakker, F. Hartl, D.J. Stufkens, W.-F. Fu and R. van Eldik
Inorg. Chem., 37, 661 (1998)

448. Mechanistic insight from energy and volume profiles for CO binding to a lacunar iron(II) cyclidene complex
M. Buchalova, D.H. Busch and R. van Eldik
Inorg. Chem., 37, 1116 (1998)

449. The double-well cage effect for a ferrocyanide/dimethylviologen ion pair in viscous media. Kinetic and thermodynamic probings through the CT transition band
D.E. Koshtariya, A. Neubrand and R. van Eldik
Chem. Phys. Lett., 284, 121 (1998)

450. Mechanistic insight from rapid-scan stopped-flow spectrophotometry into the auto­xidation of ascorbate catalysed by an iron porphyrin complex
V. Lepentsiotis and R. van Eldik
J. Chem. Soc., Dalton Trans., 999 (1998)

451. Specific chelate tuning of the substitution kinetics of platinum(II) complexes in aqueous solution
U. Fekl and R. van Eldik
Eur. J. Inorg. Chem., 389 (1998)

452. Reactive intermediates in the photodecarbonylation of the cyclopentadienyl and the indenyl complexes of CpFe(CO)2(C(O)CH3) and IndFe(CO)2(C(O)CH3) (Cp = η5-C5H5; Ind = η5-C9H7)
K.L. McFarlane, B. Lee, W.-F. Fu, R. van Eldik and P.C. Ford
Organometallics, 17, 1826 (1998)

453. Relative reactivity of N- and S-donor ligands in the substitution reactions of aquaethylenedinitrilotetraacetatoruthenium(III) in aqueous solution
H.C. Bajaj, A. Das and R. van Eldik
J. Chem. Soc., Dalton Trans., 1563 (1998)

454. Cooperative oxidation of edta by Ni(III) and dioxygen. A pulse radiolysis study
I. Zilbermann, E. Maimon, H. Cohen, R. van Eldik and D. Meyerstein
Inorg. Chem. Commun., 1, 46 (1998)

455. Regio- and stereoselective cyclization reactions of unsaturated silyl enol ethers by photoinduced electron transfer. Mechanistic aspects and synthetic approach
S. Hintz, J. Mattay, R. van Eldik and W.-F. Fu
Eur. J. Org. Chem., 1583 (1998)

456. High-pressure oxygen-17 NMR study of the dihydroxo-bridged rhodium(III) hy­drolytic dimer. Mechanistic evidence for limiting dissociative water exchange pathways
A. Drljaca, A. Zahl and R. van Eldik
Inorg. Chem., 37, 3948 (1998)

457. Structural, spectroscopic, thermodynamic and kinetic properties of copper(II) com­plexes with tripodal tetraamines
F. Thaler, C.D. Hubbard, F.W. Heinemann, R. van Eldik, S. Schindler, I. Fabian, A.M. Dittler-Klingemann, F.E. Hahn and C. Orvig
Inorg. Chem., 37, 4022 (1998)

458. Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxi­des in aqueous solution. The influence of pH, medium and aging
C. Brandt and R. van Eldik
Transition Metal Chem., 23, 667 (1998)

459. Hydrogen carbonate inhibited and induced substitution reactions of labile square- planar diethylenetriaminepalladium(II) complexes
E. Breet and R. van Eldik
Ber. Bunsenges. Phys. Chem., 102, 1418 (1998)

460. The redox kinetics of platinum(II)/(IV) complexes
K. Hindmarsh, D.A. House and R. van Eldik
Inorg. Chim. Acta, 278, 32 (1998)

461. Structural and kinetic studies on the formation of platinum(II) and palladium(II)complexes with L-cysteine-derived ligands
T. Rau, R. Alsfasser, A. Zahl and R. van Eldik
Inorg. Chem., 37, 4223 (1998)

462. Kinetics and mechanism of the ligand substitution reactions of bis(amine)-(cyclo­bu­tane-1,1-dicarboxylato)palladium(II)
A. Shoukry, T. Rau, M. Shoukry and R. van Eldik
J. Chem. Soc., Dalton Trans., 3105 (1998)

463. Investigation of the redox interaction between iron(III) 5,10,15,20-tetrakis-(p-sul­fonatophenyl)porphyrinate and aminoiminomethanesulfinic acid in aqueous solu­tion
V. Lepentsiotis, R. van Eldik, D.M. Stulov and S.V. Makarov
J. Chem. Soc., Dalton Trans., 2915 (1998)

464. Structural information on trans-1,2-diaminocyclohexane-N,N‘-tetraacetateferrate(III) in the solid and aqueous phase
S. Seibig and R. van Eldik
Inorg. Chim. Acta, 279, 37 (1998)

465. Activation and reaction volumes in solution.
A. Drljaca, C.D. Hubbard, R. van Eldik, T. Asano, M.V. Basilevsky and W.J. le Noble
Chem. Rev., 98, 2167-2289 (1998)

466. Mechanistic elucidation of small molecule – transition metal interactions by kinetic techniques
S. Schindler, C.D. Hubbard and R. van Eldik
Chem. Soc. Rev., 27, 387  (1998)

467. Complex formation of iron(II/III) with [15]aneN4 in aqueous solution. Kinetics of the oxidation of FeII([15]aneN4) by dioxygen
A. Schrodt and R. van Eldik
Inorg. React. Mechn., 1, 57 (1998)

468. Kinetics and mechanism of the reduction of pentacyanonitroferrate(III) by L-as­corbic acid in acidic aqueous solution
A. Wanat, R. van Eldik and G. Stochel
J. Chem. Soc. Dalton Trans., 2497 (1998)

469. The important role of active site water in the catalytic mechanism of human car­bonic anhydrase II. A semiempirical MO approach to the hydration of CO2
M. Hartmann, K.M Merz, Jr., R van Eldik and T. Clark
J. Mol. Model., 4, 355 (1998).

470. Kinetics and mechanism of the complexation of aqueous lanthanide ions by 4-(2-pyridylazo)resorcinol
Y. Shi, E.M. Eyring and R. van Eldik
J. Chem. Soc., Dalton Trans., 3565 (1998)

471. Effect of fumarate on the kinetics and the reaction mechanism of Cu+aq with dioxy­gen
N. Navon, H. Cohen, R. van Eldik and D. Meyerstein
J. Chem. Soc., Dalton Trans., 3663 (1998)

472. Extraction of flame retarded thermoplastic polymers by ASE
M. Rieß, T. Ernst, G. Biermann and R. van Eldik
GIT Lab. Fachz., 1008 (1998)

473. Mechanistic information from the first volume profile analysis for intramolecular electron-transfer reactions. Tetraammineruthenium(ligand) complexes of cytochro­me c
J. Sun, C. Su, M. Meier, S.S. Isied, J.F. Wishart and R. van Eldik
Inorg. Chem., 37, 6129 (1998)

474. High pressure studies in inorganic chemistry. Volume profiles for the activation of small molecules by transition metals
S. Schindler and R. van Eldik
in „High Pressure Food Science, Bioscience and Chemistry“, N.S. Isaacs (Ed.), The Royal Society of Chemistry, London, 47 (1998)

475. Analysis of flame retarded polymers and recycling materials
M. Riess, T. Ernst, R. Popp, Th. Schubert, H. Thoma, O. Vierle, G.W. Ehrenstein and R. van Eldik
Organohalogen Compounds, 35, 443 (1998)

476. Identification of brominated flame retardants in polymeric materials by reversed- phase liquid chromatography with ultraviolet detection
M. Riess and R. van Eldik
J. Chromatogr. A, 827, 65 (1998)

1999

477. Mechanistic studies in coordination chemistry
R. van Eldik
Coord. Chem. Rev., 182, 373 (1999)

478. The hydrolysis kinetics of cis-diamminedichloroplatinum(II). 10. Activation volu­mes for halide anation of some cis-[Pt(N)2(OH2)2]2+ systems
K. Hindmarsh, D.A. House and R. van Eldik
Inorg. React. Mechn., 1, 107 (1999)

479. Studies on kinetics and mechanism of imidazole substitution from cisequatorial-[Cr(S-pdtra)(Him)]0 complex in acidic and alkaline aqueous solution [S-pdtra = (S)-propy­lenediamintriacetate]
J. Chatlas, S. Kaizaki, E. Kita, P. Kita, N. Sakagami and R. van Eldik
J. Chem. Soc., Dalton Trans., 91 (1999)

480. Zinc(II) complexes of tripodal peptides mimicking the zinc(II)-coordination struc­ture of carbonic anhydrase
U. Herr, W. Spahl, G. Trojandt, W. Steglich, F. Thaler and R. van Eldik
Bioorg. Medic. Chem., 7, 699 (1999)

481. Kinetics of dissociation of the cobalt(II) and copper(II) complexes of 2,2‘,2‘‘-tris(monomethylamino)triethylamine in aqueous acidic solution
F. Thaler, C.D. Hubbard and R. van Eldik
Inorg. React. Mechn., 1, 83 (1999)

482. Multistep oxidation kinetics of [FeII(cdta)] [cdta = N,N‘,N“,N“‘-(1,2-cyclohexane-di­amine)tetraacetate] with molecular oxygen
S. Seibig and R. van Eldik
Eur. J. Inorg. Chem., 447 (1999)

483. Models for the initial stage of oxidative addition. Synthesis, characterization and mechanistic investigation of η1-I2 organometallic „pincer“ complexes of the plati­num group metals. The x-ray crystal structures of [PtI(C6H3{CH2NMe2}2-2,6)-(η1-I2)], exo-meso-[Pt(η1-I3)(η1-I2)(C6H3{CH2N(t-Bu)Me}2-2,6)] and [PdI(C6H3-{CH2NMe2}2-2,6)].(I2)2
R.A. Gossage, A.D. Ryabov, A.L. Spek, D.J. Stufkens, J.A.M. van Beek, R. van        Eldik and G. van Koten
J. Am. Chem. Soc., 121, 2488 (1999)

484. Elucidation of inorganic reaction mechanisms through volume profile analysis
G. Stochel and R. van Eldik
Coord. Chem. Rev., 187, 329 (1999)

485. Control of iron(II) spin states in 2,2′:6′,2“-terpyridine complexes through ligand substitution
E.C. Constable, G. Baum, E. Bill, R. Dyson, R. van Eldik, D. Fenske, S. Kaderli, D. Morris, A. Neubrand, M. Neuburger, D.R. Smith, K. Wieghardt, M. Zehnder and A.D. Zuberbühler
Chem. Eur. J., 5, 498 (1999)

486. Kinetics and mechanism of the base hydrolysis in cobalt(III) complexes –
The case of a complex CoLCl2+ where L has the novel topology of a square-pyra­midal NN4 coordi­nation cap
T. Poth, H. Paulus, H. Elias, R. van Eldik and A. Grohmann
Eur. J. Inorg. Chem., 643 (1999)

487. The influence of steric effects on the oxidation kinetics of [FeII(aminopolycar-box­ylato)] complexes with dioxygen
S. Seibig and R. van Eldik
Inorg. React. Mechn., 1, 91 (1999)

488. Kinetic, structural, and electrostatic aspects of the reduction of pentacyanoferra­te(III) complexes by myoglobin
E. Ilkowska, K. Lewinski, R. van Eldik and G. Stochel
J. Biol. Inorg. Chem., 4, 302 (1999)

489. The catalatic action of iron(II) complexes of 1-methyl-5,8-bis(2′-pyridylmethyl)- 1,5,8-triazacycloundecane and 1-methyl-5,9-bis(2′-pyridylmethyl)-1,5,9-triazacyclo­     do­de­cane
X. Zhang, D. Zhang, D.H. Busch and R. van Eldik
J. Chem. Soc., Dalton Trans., 2751 (1999)

490. Oxidation of benzenediols by hexabromoiridate(IV): Kinetics at ambient and ele­vated pressures
C. Ciosto, H.C. Bajaj, R. van Eldik and C.D. Hubbard
J. Chem. Soc., Dalton Trans., 1503 (1999)

491. Kinetics and mechanism of the complexation of La3+ and Cu2+ ions with N-methylacetohydroxamic acid and desferrioxamine B
M. Birus, M. Gabricevic, O. Kronja, B. Klaic, R. van Eldik and A. Zahl
Inorg. Chem., 38, 4064 (1999)

492. Inorganic and bioinorganic reaction kinetics under high pressure
R. van Eldik
High Pressure Molecular Science, R. Winter and J. Jonas (Eds.), Kluwer Academic Publishers, Dordrecht, 267 (1999)

493. Peroxynitrous acid decomposes via homolysis: Evidence from high-pressure pulse radiolysis
S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski
J. Phys. Chem. A, 103, 6587 (1999)

494. Detailed mechanistic information on methane elimination from a methyl(hydrido)-platinum(IV) complex. Relevance for the mechanism of methane activation
U. Fekl, A. Zahl and R. van Eldik
Organometallics, 18, 4156 (1999)

495. Kinetics and mechanism of the outer-sphere oxidation of horse heart cytochrome c by an anionic chromium(V) complex. Kinetic evidence for precursor formation and a  late electron-transfer transition state
M. Körner and R. van Eldik
Eur. J. Inorg. Chem., 1805 (1999)

496. Enantioselectivities in electron-transfer and excited state quenching reactions of a chiral ruthenium complex possessing a helical structure
T. Hamada, B.S. Brunschwig, K. Eifuku, E. Fujita, M. Körner, S. Sasaki, R. van Eldik and J.F. Wishart
J. Phys. Chem. A, 103, 5645 (1999)

497. Mechanistic information on the redox cycling of Ni(II/III) complexes in the presence of sulfur oxides and oxygen. Correlation with DNA damage experiments
V. Lepentsiotis, J. Domagala, I. Grgic, R. van Eldik, J.G. Muller and C.J. Burrows
Inorg. Chem., 38, 3500 (1999)

498. Structural and functional investigation on diiron complexes: Catalase-like activity and mechanistic studies on the formation of (m-peroxo)diiron(III) adducts
R. Than, A. Schrodt, L. Westerheide, R. van Eldik and B. Krebs
Eur. J. Inorg. Chem., 1537 (1999)

499. A kinetic study of the redox behaviour of FeIII(TPPS) in the presence of peroxomonosulfate, hydrogen peroxide, and sulfite/oxygen. Direct evidence for multiple redox cycling and suggested mechanisms
V. Lepentsiotis, R. van Eldik, F.F. Prinsloo and J.J. Pienaar
J. Chem. Soc., Dalton Trans., 2759 (1999)

500. Mass spectrometric analysis of nitric oxide modified caspase-3
B. Zech, M. Wilm, R. van Eldik and B. Brüne
J. Biol. Chem., 274, 20931 (1999)

501. Water exchange reactions and hydrolysis of hydrated titanium(III) ions. A density functional theory study
M. Hartmann, T. Clark and R. van Eldik
J. Phys. Chem. A, 103, 9899 (1999)

502. Kinetic and mechanistic analysis of the reactions in the aqueous system: pentacyanoferrate(II)-ammonia-nitrite
I. Maciejowska, Z. Stasicka, G. Stochel and R. van Eldik
J. Chem. Soc., Dalton Trans., 3643 (1999)