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Arbeitskreis van Eldik

2000-2004

 

2000

503. Inorganic and bioinorganic reaction mechanisms: Application of high-pressure techniques
R. van Eldik, C. Dücker-Benfer and F. Thaler
Adv. Inorg. Chem., 49, 1 (2000)

504. Identification of flame retardants in polymers using curie point pyrolysis-gas chromatography/mass spectrometry
M. Riess, H. Thoma, O. Vierle and R. van Eldik
J. Anal. Appl. Pyrolysis, 53, 135 (2000)

505. Analysis of flame retarded polymers and recycling materials
M. Riess, T. Ernst, R. Popp, B. Müller, H. Thoma, O. Vierle, M. Wolf and R. van Eldik
Chemosphere, 40, 937 (2000)

506. High pressure pulse-radiolysis as a tool in the study of transition metal reaction mechanisms
R. van Eldik and D. Meyerstein
Acc. Chem. Res., 33, 207 (2000)

507. Application of a purge and trap TDS-GC/MS procedure for the determination of emissions from flame retarded polymers
M. Wolf, M. Riess, D. Heitmann, M. Schreiner, H. Thoma, O. Vierle and R. van Eldik
Chemosphere, 41, 693 (2000)

508. Elucidation of inorganic reaction mechanisms. Application of high pressure I. Fundamental aspects, thermally induced reactions
R. van Eldik and C.D. Hubbard
Chemie in unserer Zeit, 34, 240 (2000)

509. On the mechanism of radical C-N coupling in type B semiconductor photocatalysis. A high pressure study
Reinheimer, R. van Eldik and H. Kisch
J. Phys. Chem. B, 104, 1014 (2000)

510. Aquacobalamin (Vitamin B12a) does not bind NO in aqueous solution. Nitrite impurities account for observed reaction
M. Wolak, G. Stochel, M. Hamza and R. van Eldik
Inorg. Chem., 39, 2018 (2000)

511. Correlation between spectroscopic, electrochemical and kinetic properties of cyano-bridged binuclear complexes. Analysis of temperature, pressure and solvent effects
D.E. Khoshtariya, H.C. Bajaj, P.A. Tregloan and R. van Eldik
J. Phys. Chem. A, 104, 5535 (2000)

512. Isolation and characterization of the first stable bicarbonato complexes of bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-type intermediates
Z.-W. Mao, G. Liehr and R. van Eldik
J. Am. Chem. Soc., 122, 4839 (2000)

513. Various contributions to „Catalysis from A to Z, a concise encyclopedia“
R. van Eldik
Catalysis from A to Z, B. Cornils, W.A. Herrmann, R. Schögl and C.-H. Wong (Eds), Wiley-VCH, Weinheim, 2000.

514. Elucidation of inorganic reaction mechanisms. Application of high pressure II. Electron transfer, photo and radiation induced reactions
R. van Eldik and C.D. Hubbard
Chemie in unserer Zeit, 34, 306 (2000)

515. Substitution behaviour of an alkylcobaltammine complex. Evidence for a limiting dissociative mechanism
Dücker-Benfer, M.S.A. Hamza, C. Eckhardt and R. van Eldik
Eur. J. Inorg. Chem., 1563 (2000)

516. Quantification of heavy metals for the recycling of waste plastics from electrotechnical applications
T. Ernst, R. Popp and R. van Eldik
Talanta, 53, 347 (2000)

517. Ligand substitution behaviour of a simple model for coenzyme B12
M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik
Inorg. Chem., 39, 3777, 6145 (2000)

518. A new cylindrical, six-membered iron(III) cluster consisting of three oxo-bridged diiron subunits linked by carboxylate bridges
T. Schneppensieper, G. Liehr, R. van Eldik, J. Ensling and P. Gütlich
Inorg. Chem., 39, 5565 (2000)

519. Effects of trifluoromethyl substituents in a tris(pyrazolyl)borate ligand: A structural and spectroscopic study of analogous Pt(IV) trimethyl complexes
U. Fekl, R. van Eldik, S. Lovell and K.I. Goldberg
Organometallics, 19, 3535 (2000)

520. Kinetics and mechanism of the carbonate ion inhibited aqueous ozone decomposition
A. Neves, I. Fabian and R. van Eldik
J. Phys. Chem. A, 104, 7995 (2000)

521. Mechanistic differences between „reductive“ and „oxidative“ heterolysis of metal-carbon s bonds
N. Shaham, H. Cohen, R. van Eldik and D. Meyerstein
J. Chem. Soc., Dalton Trans., 3356 (2000)

522. Evidence for adduct formation between ONOO and CO2 from high pressure pulse radiolysis
S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski
J. Phys. Chem. A, 104, 9712 (2000)

523. Fog, spot, fanfare – how students can still learn chemistry
A. Kerk, C. Dücker-Benfer, T. Schneppensieper, B. Müller, M. Galle, R. van Eldik, C. Felser, F. Renz, W. Tremel, R. Zimehl and M. Drieß
Nachr. Chem., 48, 1481 (2000)

524. Elucidation of inorganic reaction mechanisms. Application of high pressure
R. van Eldik and C.D. Hubbard
SA Journal of Chemistry, 53, 139-168 (2000)

525. Ionic and hydrogen bonding dynamics coupled to optical and thermal electron transfer. Temperature, pressure and viscosity effects
D.E. Khoshtariya, T.D. Dolidze, A. Neubrand and R. van Eldik
J. Mol. Liq., 89, 127 (2000)

2001

526. Thermodynamic and kinetic studies on complex-formation reactions of a cobalt(II) tripodal tetraamine complex
Z.-L. Lu, M.S.A. Hamza and R. van Eldik
Eur. J. Inorg. Chem., 503-510 (2001)

527. Tuning the reversible binding of NO to iron(II) aminocarboxylate and related complexes in aqueous solution
T. Schneppensieper, S. Finkler, A. Czap, R. van Eldik, M. Heus, P. Nieuwenhuizen, C. Wreesmann and W. Abma
Eur. J. Inorg. Chem., 491-501 (2001)

528. Mechanistic studies on the reversible binding of nitric oxide to metmyoglobin
L.E. Laverman, A. Wanat, J. Oszajca, G. Stochel, P.C. Ford and R. van Eldik
J. Am. Chem. Soc., 123, 285-293 (2001)

529. Kinetics and mechanism of water substitution in half-sandwich iridium(III) aqua cations Cp*Ir(A-B)(H2O)2+/+ in aqueous solution (Cp* = h5-pentamethylcyclo-pentadienyl anion; A-B = bidentate N,N or N,O ligand)
T. Poth, H. Paulus, H. Elias, C. Dücker-Benfer and R. van Eldik
Eur. J. Inorg. Chem., 1361-1369 (2001)

530. Thermodynamic and kinetic studies on the reaction between the vitamin B12 derivative (N-methylimidazole)cobalamin and N-methylimidazole: Ligand displacement at the a axial site of cobalamins by an imidazole type ligand
A.G. Cregan, N.E. Brasch and R. van Eldik
Inorg. Chem., 40, 1430-1438 (2001)

531. Mechanistic studies on the metal catalyzed autoxidation of sulfur(IV) oxides
R. van Eldik
Dynamics and Chemistry of Hydrometeors, R. Jaenicke (Ed.), Wiley-VCH, Weinheim, 387-399 (2001)

532. A bowl-shaped and highly inert bis-(m-hydroxo)-platinum(II) dimer
U. Fekl, R. van Eldik, C. Richardson and W.T. Robinson
Inorg. Chem., 40, 3247-3251 (2001)

533. Controlling the lability of square planar Pt(II) complexes through electronic communication between p-acceptor ligands
D. Jaganyi, A. Hofmann and R. van Eldik
Angew. Chem. Int. Ed., 40, 1680-1683 (2001)

534. Water exchange controls the complex-formation mechanism of water-soluble iron(III) porphyrins. Conclusive evidence for dissociative water exchange from a high pressure 17O NMR study
T. Schneppensieper, A. Zahl and R. van Eldik
Angew. Chem. Int. Ed., 40, 1678-1680 (2001)

535. Electrostriction and counter ion effects in an outer-sphere electron transfer reaction. Kinetics of the reduction of hexachloroiridate(IV) by iodide ion
C.D. Hubbard, A. Gerhard and R. van Eldik
J. Chem. Soc., Dalton Trans., 1069-1075 (2001)

536. Structural and mechanistic information on the reaction of bicarbonate with Cu(II) and Zn(II) complexes of tris(2-aminoethyl)amine. Identification of intermediate and product species
Z.-W. Mao, G. Liehr and R. van Eldik
J. Chem. Soc., Dalton Trans., 1593-1660 (2001)

537. A high pressure pulse-radiolysis study of the formation and decomposition of complexes with iron-carbon s bonds. A mechanistic comparison for different metal centers
S. Goldstein, G. Czapski, R. van Eldik, N. Shaham, H. Cohen and D. Meyerstein
Inorg. Chem., 40, 4966-4970 (2001)

538. Influence of chelate effects on the water exchange mechanism of polyaminecarboxylate complexes of iron(III)
T. Schneppensieper, S. Seibig, A. Zahl, P. Tregloan and R. van Eldik
Inorg. Chem., 40, 3670-3676 (2001)

539. Ligand effects on the kinetics of the reversible binding of NO to selected iron(II) aminocarboxylate complexes in aqueous solution
T. Schneppensieper, A. Wanat, G. Stochel, S. Goldstein, D. Meyerstein and R. van Eldik
Eur. J. Inorg. Chem., 2317-2325 (2001)

540. Electron transfer reaction between cytochrome c and trisoxalatocobalt(III)
J. Macyk and R. van Eldik
J. Chem. Soc., Dalton Trans., 2288-2292 (2001)

541. Kinetics and mechanism of the reversible binding of nitric oxide to reduced cobalamin B12r
M. Wolak, A. Zahl, T. Schneppensieper, G. Stochel and R. van Eldik
J. Am. Chem. Soc., 123, 9780-9791 (2001)

542. Equilibrium and kinetic studies on the reactions of alkylcobalamins with cyanide
M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik
Inorg. Chem., 40, 5440-5447 (2001)

543. Complex-formation reactions of Cu(II) and Zn(II) 2,2′-bipyridine and 1,10-phenanthroline complexes with bicarbonate. Identification of different carbonate coordination modes
Z.-W. Mao, F.W. Heinemann, G. Liehr and R. van Eldik
J. Chem. Soc., Dalton Trans., 3652-3662 (2001)

2002

544. Nitrite binding to metmyoglobin and methemoglobin in comparison to nitric oxide binding
A. Wanat, J. Gdula-Argasinska, D. Rutkowska-Zbik, M. Witko, G. Stochel and R. van Eldik
J. Biol. Inorg. Chem., 7, 165-176 (2002)

545. Five-coordination and adduct formation in Co(III) corrinoids: Dissecting ligand substitution into its component parts
M.S.A. Hamza, R. van Eldik, P.L.S. Harper, J.M. Pratt and E.A. Betterton
Eur. J. Inorg. Chem., 580-583 (2002)

546. Kinetics, mechanism and spectroscopy of the reversible binding of nitric oxide to aquated iron(II). An undergraduate text book reaction revisited
A. Wanat, T. Schneppensieper, G. Stochel, R. van Eldik, E. Bill and K. Wieghardt
Inorg. Chem., 41, 4-10 (2002)
This manuscript is featured on the cover of the January 14, 2002 issue of Inorganic Chemistry!

547. 139La NMR kinetic study of lanthanum(III) complexation with acetohydroxamic acid
M. Birus, R. van Eldik, M. Gabricevic and A. Zahl
Eur. J. Inorg. Chem., 819-825 (2002)

548. Kinetics and mechanism of the reaction of chelated Pd(II) complexes with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pd(bpma)Cl]Cl.H2O (bmpa = bis(2-pyridylmethyl)amine)
Z.D. Bugarcic, G. Liehr and R. van Eldik
J. Chem. Soc., Dalton Trans., 951-956 (2002)

549. Die Zaubervorlesung: „Chemie am laufenden Band“
B. Müller, M. Galle, T. Schneppensieper, C. Dücker-Benfer and R. van Eldik
Chemie in unserer Zeit, 36, 246-255 (2002)

550. High Pressure Chemistry: Synthetic, Mechanistic and Supercritical Applications
R. van Eldik and F.-G. Klärner (Eds.)
VCH-Wiley, Weinheim, Germany, 485 pp, 2002.

551. The substitution mechanism of [RuIII(edta)(H2O)] with DNA bases, nucleosides and nucleotides in aqueous solution revisited
D. Chatterjee, A. Mitra, M.S.A. Hamza and R. van Eldik
J. Chem. Soc., Dalton Trans., 962-965 (2002)

552. „Phantom activation volumes“ are indeed real activation volumes
C.F. Weber and R. van Eldik
J. Phys. Chem. A, 106, 6904-6908 (2002)

553. Effect of pressure on inorganic reactions. Introduction and mechanistic applications
R. van Eldik and C.D. Hubbard
in „High Pressure Chemistry: Synthetic, Mechanistic and Supercritical Applications“, R. van Eldik and F.-G. Klärner (Eds.), VCH-Wiley, Weinheim, Germany, p. 3-40, 2002.

554. Effect of pressure on electron transfer reactions in inorganic and bioinorganic chemistry
J. Macyk and R. van Eldik
in „Frontiers in High Pressure Biochemistry and Biophysics“, Biochim. Biophys. Acta, 1595, 283-296 (2002).

555. Equilibrium, kinetic and leaving group effect studies on ligand substitution reactions of a simple model for coenzyme B12
B.M. Alzoubi, M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik
Eur. J. Inorg. Chem., 968-974 (2002)

556. Cation-independent electron transfer between ferricyanide and ferrocyanide ions in aqueous solution
A. Zahl, R. van Eldik and T.W. Swaddle
Inorg. Chem., 41, 757-764 (2002)

557. Mechanism of water exchange on five-coordinate copper(II) complexes
A. Neubrand, F. Thaler, M. Körner, A. Zahl, C.D. Hubbard and R. van Eldik
J. Chem. Soc., Dalton Trans., 957-961 (2002)

558. To be or not to be NO in coordination chemistry? A mechanistic approach
M. Wolak and R. van Eldik
Coord. Chem. Rev., 230, 263-282 (2002)

559. Thermodynamics and kinetics of RuIII(edta) as efficient scavenger for nitric oxide in aqueous solution
A. Wanat, T. Schneppensieper, A. Karocki, G. Stochel and R. van Eldik
J. Chem. Soc., Dalton Trans., 941-950 (2002)

560. Ligand effects on the reactivity of Cu(I)L complexes toward Cl3CCO2
N. Navon, A. Burg, H. Cohen, R. van Eldik and D. Meyerstein
Eur. J. Inorg. Chem., 423-429 (2002)

561. Liquid water (D2O): A dynamic model emerging from near-infrared DO-D stretching overtone studies
D.E. Koshtariya, T.D. Dolidze, P. Lindquist-Reis, A. Neubrand and R. van Eldik
J. Mol. Liq., 96/97, 45-63 (2002)

562. Mechanistic information from pressure acceleration of hydride formation via proton binding to a cobalt(I) macrocycle
E. Fujita, J.F. Wishart and R. van Eldik
Inorg. Chem., 41, 1579-1583 (2002)

563. Laser flash photolysis as tool in the elucidation of the nitric oxide binding mechanism to metallobiomolecules
A. Wanat, M. Wolak, L. Orzel, M. Brindell, R. van Eldik and G. Stochel
Coord. Chem. Rev., 229, 37-49 (2002)

564. Mechanistic information on the reversible binding of NO to selected iron(II) chelates from activation parameters
T. Schneppensieper, A. Wanat, G. Stochel and R. van Eldik
Inorg. Chem., 41, 2565-2573 (2002)

565. Solvation largely accounts for the effect of N-alkylation on the properties of nickel(II/I) and chromium(III/II) cyclam complexes
T. Clark, M. Hennemann, R. van Eldik and D. Meyerstein
Inorg. Chem., 41, 2927-2935 (2002)

566. Activation volume measurement for C-H activation. Evidence for associative benzene substitution at a platinum(II) center
J. Procelewska, A. Zahl, R van Eldik, H.A. Zhong, J.A. Labinger and J.E. Bercaw
Inorg. Chem., 41, 2808-2810 (2002)

567. Sovatochromism and piezochromism of dicyano-, tricyano-, and tetracyano-diimine-iron(II) complexes
A. Alousy, N.J. Blundell, J. Burgess, C.D. Hubbard and R. van Eldik
Transition Met. Chem., 27, 244-252 (2002)

568. Kinetics and mechanism of the reactions of [Pt(terpy)H2O]2+ with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pt(terpy)(tu)](ClO4)2 (tu = thiourea)
Z. Bugarcic, G. Liehr and R. van Eldik
J. Chem. Soc., Dalton Trans., 2825-2830 (2002)

569. Mechanistic insight from a volume profile for electron transfer between promazine and hexaaquairon(III)
J. Wisniewska and R. van Eldik
Inorg. Chem., 41, 3802-3804 (2002)

570. A detailed mechanistic study of the behaviour of an unusual seven-coordinate iron(III) complex in aqueous solution
I. Ivanovic-Burmazovic, M.S.A. Hamza and R. van Eldik
Inorg. Chem., 41, 5150-5161 (2002)

571. Kinetics and mechanism of the formation of nitroprusside from aquapentacyanoferrate(III) and NO. Complex-formation is controlled by outer-sphere electron transfer
F. Roncaroli, J.A. Olabe and R. van Eldik
Inorg. Chem., 41, 5417-5425 (2002)

572. Equilibrium and kinetic data for the interaction of diaqua-(S-methyl-L-cysteine)palladium(II) with biologically relevant ligands
Z.D. Bugarcic, M.M. Shoukry and R. van Eldik
J. Chem. Soc., Dalton Trans., 3945-3951 (2002)

573. Detailed kinetic and thermodynamic studies on the cyanation of alkylcobalamins. A generalized mechanistic description
M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik
J. Chem. Soc., Dalton Trans., 3832-3839 (2002)

574. Substitution behaviour of an unusual seven-coordinate iron(III) complex in different solvents
I. Ivanovic-Burmazovic, M.S.A. Hamza and R. van Eldik
Inorg. Chem. Commun., 5, 937-940 (2002)

575. Reactions of methyl viologen and nitrite with thiourea dioxide. New opportunities for an old reductant.
S.V. Makarov, E.V. Kudrik, R. van Eldik and E.V. Naidenko
J. Chem. Soc., Dalton Trans., 4074-4076 (2002)

576. Photochemistry of concentrated sulfuric acid in the presence of SO2 and Fe(II), and implications for the cloud chemistry of Venus
G.A. Rowland, R. van Eldik and L.F. Phillips
J. Photochem. Photobiol. A, 153, 1-10 (2002)

577. Haemoglobins with multiple reactive sulfhydryl groups: reactions of 5,5’-dithiobis(2-nitrobenzoate) with CysF9[93]b and CysH3[125]b of guinea pig haemoglobin
J.O. Babelola, L.U. Uko, K.O. Okonjo and R. van Eldik
Bull. Chem. Soc. Ethiopia, 16, 175-186 (2002)

2003

578. Analysis of eco-relevant elements and noble metals in printed wiring boards using AAS, ICP-AES and EDXRF
T. Ernst, R. Popp, M. Wolf and R. van Eldik
Anal. Bioanal. Chem., 375, 805-814 (2003)

579. Thermodynamic and kinetic data for the base-on/base-off equilibration of alkylcobalamins
M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik
Eur. J. Inorg. Chem., 268-276 (2003)

580. Molecular orbital and DFT studies on water exchange mechanisms of metal ions
H. Erras-Hanauer, T. Clark and R. van Eldik
Coord. Chem. Rev., 238-239, 233-253 (2003)

581. Structures of carbonato and bicarbonato complexes of bis(1,10-phenanthroline)-zinc(II): experiment and theory
H. Erras-Hanauer, Z.-W. Mao, G. Liehr, T. Clark and R. van Eldik
Eur. J. Inorg. Chem., 1562-1569 (2003)

582. Kinetics and mechanism of the cobalt phthalocyanine catalyzed reduction of nitrite and nitrate by dithionite in aqueous solution
E.V. Kudrik, S.V. Makarov, A. Zahl and R. van Eldik
Inorg. Chem., 42, 618-624 (2003)

583. Mechanistic studies on the interaction of reduced cobalamin (vitamin B12r) with nitroprusside
M. Wolak, G. Stochel and R. van Eldik
J. Am. Chem. Soc., 125, 1334-1351 (2003)

584. Interaction of  [RuIII(edta)H2O] with amino acids in aqueous solution. Equilibrium, kinetic and protease inhibition studies
D. Chatterjee, M.S.A. Hamza, M.M. Shoukry, A. Mitra, S. Deshmukh and R. van Eldik
Dalton Trans., 203-209 (2003)

585. Electronic tuning of the lability of Pt(II) complexes through p-acceptor effects. Correlations between thermodynamic, kinetic and theoretical parameters
A. Hofmann, D. Jaganyi, O.Q. Munro, G. Liehr and R. van Eldik
Inorg. Chem., 42, 1688-1700 (2003)

586. The reaction between methylcobalamin and cyanide revisited
S.J. Brodie, A.G. Cregan, R. van Eldik and N.E. Brasch
Inorg. Chim. Acta, 348, 221-224 (2003)

587. The unusually fast reaction between ruthenium(III)-ammine complexes and NO revisited
A. Czap and R. van Eldik
Dalton Trans., 665-671 (2003)

588. Mechanistic insight from activation parameters for the reaction between coenzyme B12 and cyanide: Further evidence that heterolytic Co-C bond cleavage is solvent-assisted
M.S.A. Hamza, A.G. Cregan, N.E. Brasch and R. van Eldik
Dalton Trans., 596-602 (2003)

589. Complex-formation reactions and stability constants for mixed-ligand complexes of diaqua(2-picolylamine)palladium(II) with some bio-relevant ligands
A.A. El-Sherif, M.M. Shoukry and R. van Eldik
Dalton Trans., 1425-1432 (2003)

590. Outer-sphere electron-transfer between horse heart cytochrome c and anionic Cu(II/I) complexes. Evidence for precursor formation and coordination sphere reorganization for electron transfer
M. Koerner, P.A. Tregloan and R. van Eldik
Dalton Trans., 2710-2717 (2003)
This manuscript is featured on the inside cover of the July 7, 2003 issue of Dalton Transactions!

591. Self-exchange reactions of metallocenes revisited: Insights from the decamethylferricinium-decamethylferrocene reaction at variable pressure
A. Zahl, R. van Eldik, M. Matsumoro and T.W. Swaddle
Inorg. Chem., 42, 3718-3722 (2003)
This manuscript is featured on the cover of the June 16, 2003 issue of Inorganic Chemistry!

592. Mechanistic insight gained into the ligand substitution reactions of (triphenylphosphine)bis(o-benzosemiquinonediiminato)cobalt(III). Kinetic, solvent and volume profile studies
B.M. Alzoubi, M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik
Eur. J. Inorg. Chem., 2972-2978 (2003)

593. Kinetics of the reduction of cytochrome c by [FeII(edta)H2O]2-. Outer-sphere versus inner-sphere electron transfer mechanisms
J. Macyk and R. van Eldik
Dalton Trans., 2704-2709 (2003)

594. Kinetics and mechanism of the interaction of nitric oxide with pentacyanoferrate(II). Formation and dissociation of [Fe(CN)5NO]3-
F. Roncaroli, J.A. Olabe and R. van Eldik
Inorg. Chem., 42, 4179-4189 (2003)

595. A compact high pressure unit for UV-VIS-NIR spectroscopic measurements at pressures up to 400 MPa
A. Zahl, P. Igel, M. Weller, D. Koshtariya, M.S.A. Hamza and R. van Eldik
Rev. Sci. Instrum., 74, 3758-3762 (2003)

596. Electrostatic complexation and photo-induced electron transfer between Zn-cytochrome c and polyanionic fullerene dendrimers
M. Braun, S. Atalick, D.M. Guldi, H. Lanig, M. Brettreich, S. Burghardt, M. Hatzimarinaki, E. Ravanelli, M. Prato, R. van Eldik and A. Hirsch,
Chem. Eur. J., 9, 3867-3875 (2003)

597. Coenzyme B12 model studies. Kinetics of axial ligation of alkyl cobalt complexes containing a tridentate amino-oximate ligand
B.M. Alzoubi, M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik
Eur. J. Inorg. Chem., 3738-3744 (2003)

598. Positive activation volume for a cytochrome c electrode process: Evidence for a “protein friction” mechanism from high pressure studies
T.D. Dolidze, D.E. Khoshtariya, D.H. Waldeck, J. Macyk and R. van Eldik
J. Phys. Chem. B, 107, 7172-7179 (2003)

599. Kinetic and thermodynamic studies on the cyanation reactions and base-on/base-off equilibria of alkyl-13-epicobalamins
M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik
Dalton Trans., 2986-2991 (2003)

600. Advances in Inorganic Chemistry, Vol. 54: Inorganic Reaction Mechanisms
R. van Eldik and C.D. Hubbard (Eds)
Academic Press, San Diego, 477 pp, 2003

601. Thermodynamic and kinetic study of the interaction between the Pt(II) centres in [Pt2(N,N,N’,N’-tetrakis(2-pyridylmethyl)diamine)(H2O)2]4+. Influence of the bridging ligand
A. Hofmann and R. van Eldik
Dalton Trans., 2979-2985 (2003)

602. Magic Show 2003
W. Schießl, A. Hofmann, C. Dücker-Benfer, N. Summa, M. Galle and R. van Eldik
GIT Labor Fachz., 614-616 (2003)

603. Extraction of brominated flame retardants from polymeric waste material using different solvents and supercritical carbon dioxide
A. mnim Altwaiq, M. Wolf and R. van Eldik
Anal. Chim. Acta, 491, 111-123 (2003)

604. Cyclometallated analogues of platinum terpyridine complexes: Kinetic study of the strong s-donor cis and trans effects of carbon in the presence of a p-acceptor ligand backbone
A. Hofmann, L. Dahlenburg and R. van Eldik
Inorg. Chem., 42, 6528-6538 (2003)

605. Evaluation of activation volumes for the conversion of peroxynitrous to nitric acid
R. Kissner, C. Thomas, M.S.A. Hamza, R. van Eldik and W.H. Koppenol
J. Phys. Chem. A, 107, 11261-11263 (2003)

2004

606. Highly localized charges control electrostriction. Reaction volumes for the reduction of mononuclear and bridged Ru complexes
H.C. Bajaj, P.A. Tregloan and R. van Eldik
Inorg. Chem., 43, 1429-1435 (2004)

607. Mechanistic information on the copper-catalysed autoxidation of mercaptosuccinic acid in aqueous solution
M. Pawelec, G. Stochel and R. van Eldik
Dalton Trans., 292-298 (2004)

608. The profound influence of a single metal-carbon bond on the reactivity of bio-relevant cobalt(III) complexes
M.S.A. Hamza and R. van Eldik
Dalton Trans., 1-12 (2004)
This manuscript is featured on the cover of the January 7, 2004 issue of Dalton Transactions!

609. Substitution reactions of [Pt(terpy)X]2+ with some biologically relevant ligands. Synthesis and crystal structures of [Pt(terpy)(cyst-S)](ClO4)2.0.5H2O and [Pt(terpy)(guo-N7)](ClO4)2.0.5guo.1.5H2O
Z.D. Bugarcic, F.W. Heinemann and R. van Eldik
Dalton Trans., 279-286 (2004)

610. Mechanistic studies on a facile ring-flipping process in planar-chiral ferrocenes under ambient and high pressure and its relevance to symmetric catalysis
O.J. Curnow, G.M. Fern, M.L. Hamilton, A. Zahl and R. van Eldik
Organometallics, 23, 906-912 (2004)

611. Electronically and sterically tuned trans labilization controls the substitution behaviour of cobaloximes
M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik
Dalton Trans., 287-291 (2004)

612. Role of chelate substituents and cis s-effects on the rate of ligand substitution at Pt(N-N-N) and Pt(N-N-C) centres
D. Jaganyi, D. Reddy, J.A. Gertenbach, A. Hofmann and R. van Eldik
Dalton Trans., 299-304 (2004)

613. Kinetics and mechanism of water substitution in the low spin Fe(II) complex of 4-octasulfophenylpyrazinoporphyrazine
E.V. Kudrik, R. van Eldik and S.V. Makarov
Dalton Trans., 429-435 (2004)

614. Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents
B.M. Alzoubi, M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik
Eur. J. Inorg. Chem., 653-659 (2004)
This manuscript is featured on the cover of the February 6, 2004 issue of Eur. J. Inorg. Chem.!

615. NO Binding to cobalamin: Influence of the metal oxidation state
C. Selçuki, R. van Eldik and T. Clark
Inorg. Chem., 43, 2828-2833 (2004)

616. Effect of inhibitors on the catalyzed dehydration of HCO3 by copper(II) complexes re-evaluated
R. van Eldik
Inorg. Chem., 43, 2756-2758 (2004)

617. Substrate binding favours enhanced NO binding to P450cam
A. Franke, G. Stochel, C. Jung and R. van Eldik
J. Am. Chem. Soc., 126, 4181-4191 (2004)

618. Advances in Inorganic Chemistry, Vol. 55
R. van Eldik (Ed)
Elsevier Academic Press, San Diego, 447 pp, 2004

619. Structure and characterization of non-cyclic tetraaza complexes of copper(II) and their reactions with nitric oxide
C.-H. Kwak, J.-E. Jee, M. Pyo, J. Kim and R. van Eldik
Inorg. Chim. Acta, 357, 2643-2649 (2004)

620. Further mechanistic information on the reaction between FeIII(edta) and hydrogen peroxide. Observation of a second reaction step and importance of pH
A. Brausam and R. van Eldik
Inorg. Chem., 43, 5351-5359 (2004)

621. A new high-pressure NMR probe designed for a narrow bore magnet system
A. Zahl, P. Igel, M. Weller and R. van Eldik
Rev. Sci. Instrum., 75, 3152-3157 (2004)

622. Mechanistic elucidation of the substitution behavior of alkyl cobaloximes in water and methanol as solvents
B.M. Alzoubi, G. Liehr and R. van Eldik
Inorg. Chem., 43, 6093-6100 (2004)

623. Local dense structural heterogeneities in liquid water from ambient to 300 MPa pressure: Evidence for multiple liquid-liquid transitions
D.E. Khoshtariya, A. Zahl, T.D. Dolidze, A. Neubrand and R. van Eldik
ChemPhysChem, 5, 1398-1404 (2004)

624. The role of positively charged meso-substituents on the kinetics of the reductive nitrosylation of iron(III)-porphyrins. The catalytic role of nitrite
A. Theodoridis and R. van Eldik
J. Mol. Cat. A, 224, 197-205 (2004)

625. Advances in Inorganic Chemistry, Vol. 56: Redox-active metal complexes
R. van Eldik (Ed)
Elsevier Academic Press, San Diego, 273 pp, 2004

626. Discrimination of diverse (pressure/temperature-dependent/independent) inherent sub-structures in liquid water (D2O) from difference vibrational spectroscopy
D.E. Khoshtariya, A. Zahl, T.D. Dolidze, A. Neubrand and R. van Eldik
J. Phys. Chem. B, 108, 14796-14799 (2004)

627. Comparison of thermodesorption and soxhlet extraction for GC/MS analysis of plastic additives
M. Pöhlein, B. Müller, M. Wolf and R. van Eldik
GIT Labor-Fachzeitschrift, 754-758 (2004)

628. The influence of terpyridine as p-acceptor ligand on the kinetics and mechanism of the reaction of NO with ruthenium(III) complexes
A. Czap, F.W. Heinemann and R. van Eldik
Inorg. Chem., 43, 7832-7843 (2004)

629. Kinetic and mechanistic study on the reaction of alkylcobaloximes with azoles
M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik
Dalton Trans., 3835-3839 (2004)

630. Evidence for associative ligand exchange processes on solvated lithium cations
R. Puchta, M. Galle, N.J.R. van Eikema Hommes, E. Pasgreta and R. van Eldik
Inorg. Chem., 43, 8227-8229 (2004)